Structural, Morphological and Tensile Study of CdS/Polystyrene (PS) Nanocomposite

Authors

  • Vishal Mathur Department of Engineering Physics, Kautilya Institute of Technology & Engineering, ISI-16, Riico Institutional AreaSitapura, Jaipur-302004, India
  • Kananbala Sharma Semiconductor and Polymer Science Laboratory, 5-6, Vigyan Bhawan, University of Rajasthan, Jaipur-302004, India

DOI:

https://doi.org/10.6000/1929-5995.2013.02.02.3

Keywords:

Nanocomposite, SAXS analysis, mechanical properties, tensile properties

Abstract

Thick film of CdS/Polystyrene (PS) nanocomposite was synthesized by dispersing nanofiller particles of CdS in PS matrix. The nanostructure of the CdS particles has been ascertained through X-ray Diffraction (XRD) and Transmission Electron Microscopy (TEM). Small angle x-ray scattering analysis has been performed in order to ascertain nanocomposite character of the PS/CdS sample. Scanning Electron Microscopy (SEM) analyses of these samples have been carried out to establish the surface morphology. The Tensile studies of prepared samples have been ascertained through Dynamic Mechanical Analyzer (DMA). This study reveals that the young’s modulus and the toughness of the material are greatly influenced by the existence of interfacial energetic interaction between dispersed CdS nanofiller particles and matrix of PS.

References

Z, Yang JL, Friedrich K. Creep resistant polymeric nanocomposites. Polymer 2004; 45: 3481. http://dx.doi.org/10.1016/j.polymer.2004.03.004

Martin CR, Pauli MAD. Antistatic thermoplastic blend of polyaniline and polystyrene prepared in a double screw extruder. Eur Polym J 2005; 41: 2867.

Godovsky DYu. Device applications of polymer-nanocomposites. Adv Polym Sci 2000; 153: 163.

Caseri WM. Nanocomposites of polymers and metals or semiconductors: Historical background and optical properties. Rapid Commun 2000; 21: 705. http://dx.doi.org/10.1002/1521-3927(20000701)21:11<705::AID-MARC705>3.0.CO;2-3

Moffitt M, Eisenberg A. Size Control of Nanoparticles in Semiconductor-Polymer Composites. 1. Control via Multiplet Aggregation Numbers in Styrene-Based Random Ionomers. Chem Mater 1995; 7: 1178. http://dx.doi.org/10.1021/cm00054a017

Moffitt M, McMahon L, Pessel V, Eisenberg A. Size Control of Nanoparticles in Semiconductor-Polymer Composites. 2. Control via sizes of spherical Ionic microdomains in Styrene Based Diblock Ionomers. Chem Mater 1995; 7: 1185. http://dx.doi.org/10.1021/cm00054a018

Du H, Xu GQ, Chin WS, Huang L, Ji W. Synthesis, Characterization and Nonlinear Optical Properties of Hybridized CdS-polystyrene Nanocomposites. Chem Mater 2002; 4473. http://dx.doi.org/10.1021/cm010622z

Mathur V, Dixit M, Rathore KS, Saxena NS, Sharma KB. Tensile Study of PVC-CdS Semiconducting Nanocomposite. Rap Commun J Opteo Elect Adv Mat 2009; 7: 685.

Rathore KS, Patidar D, Janu Y, Saxena NS, Sharma KB, Sharma TP. Structural and Optical Characterization of Chemically Synthesized ZnS Nanoparticles. Chalcogen Lett 2008; 6: 105.

Favier V, Canova GR, Shrivastava SC, Cavaille JY. Mechanical percolation in cellulose whisker nanocomposites. Polym Engg Sci 1997; 37: 1732. http://dx.doi.org/10.1002/pen.11821

Chazeau L, Cavaille JY, Canova G, Dendievel R, Boutherin B. Viscoelastic properties of plasticized PVC reinforced with cellulose whiskers. J Appl Polym Sci 1999; 71: 1797. http://dx.doi.org/10.1002/(SICI)1097-4628(19990314)71:11<1797::AID-APP9>3.0.CO;2-E

Mathur V, Dixit M, Saxena NS, Sharma KB. Morphological Effects on Mechanical properties of Polystyrene-Polyvinylchloride blends. Phase Transitions 2009; 11: 769. http://dx.doi.org/10.1080/01411590903445089

Menard K. Dynamic Mechanical Analysis, A Practical Introduction; LLC: CRC Press, 1999; pp. 61-64 and 94-100.

Ahmad Z, Awadi NAA, Sagheer FA. Morphology, thermal stability and visco-elastic properties of polystyrene–poly(vinyl chloride) blends. Polym Degrad Stab 2007; 92: 1025. http://dx.doi.org/10.1016/j.polymdegradstab.2007.02.016

Downloads

Published

2013-06-25

Issue

Section

Articles

How to Cite

Structural, Morphological and Tensile Study of CdS/Polystyrene (PS) Nanocomposite. (2013). Journal of Research Updates in Polymer Science, 2(2), 105-109. https://doi.org/10.6000/1929-5995.2013.02.02.3

Similar Articles

1-10 of 170

You may also start an advanced similarity search for this article.