Investigation on Microstructure and Optical Property of Nanocrystalline Silicon Thin Film

Authors

  • Li-Qiang Guo Micro/Nano Science & Technology Center, Jiangsu University, 212013, Zhenjiang, China
  • Jian-Ning Ding Micro/Nano Science & Technology Center, Jiangsu University, 212013, Zhenjiang, China
  • Guang-Gui Cheng Micro/Nano Science & Technology Center, Jiangsu University, 212013, Zhenjiang, China
  • Zhi-Yong Ling Micro/Nano Science & Technology Center, Jiangsu University, 212013, Zhenjiang, China
  • Zhong-Qiang Zhang Micro/Nano Science & Technology Center, Jiangsu University, 212013, Zhenjiang, China

DOI:

https://doi.org/10.6000/2369-3355.2014.01.02.3

Keywords:

PECVD, process conditions, optical property, microstructure.

Abstract

Nanocrystalline silicon (nc-Si:H) thin films were deposited by capacitive coupled radio-frequency plasma enhanced chemical vapor deposition (RF-PECVD) system with direct current (DC) bias applied. Raman, XRD and ultraviolet-visible transmission spectra were employed to investigate their microstructure and optical properties, respectively. Both the crystalline volume fraction and the average crystalline size increase with the substrate temperature. With the increase of silane concentration, the crystalline volume fraction increases, while the average crystalline size decreases. With the increase of the radio frequency (RF) power or the DC negative bias voltage, the crystalline volume fraction and the average crystalline size increase firstly, then decreases. Finally, the optical band gaps were discussed in detail.

Author Biographies

  • Li-Qiang Guo, Micro/Nano Science & Technology Center, Jiangsu University, 212013, Zhenjiang, China

    Micro/Nano Science & Technology Center

  • Jian-Ning Ding, Micro/Nano Science & Technology Center, Jiangsu University, 212013, Zhenjiang, China

    Micro/Nano Science & Technology Center

  • Guang-Gui Cheng, Micro/Nano Science & Technology Center, Jiangsu University, 212013, Zhenjiang, China

    Micro/Nano Science & Technology Center

  • Zhi-Yong Ling, Micro/Nano Science & Technology Center, Jiangsu University, 212013, Zhenjiang, China

    Micro/Nano Science & Technology Center

  • Zhong-Qiang Zhang, Micro/Nano Science & Technology Center, Jiangsu University, 212013, Zhenjiang, China

    Micro/Nano Science & Technology Center

References

Biswas R, Bhattacharya J, Lewis B, Chakravarty N, Dalal V. Enhanced nanocrystalline silicon solar cell with a photonic crystal back-reflector. Sol Energ Mat Sol C 2010; 94: 2337-42. http://dx.doi.org/10.1016/j.solmat.2010.08.007

Peng YC, He YL. Research & development on fabrications, structures and properties of nanometer silicon film materials. Chin J Rare Metals 1999; 23: 42-55.

Waman VS, Kamble MM, Pramod MR, et al. Influence of the deposition parameters on the microstructure and opto-electrical properties of hydrogenated nanocrystalline silicon films by HW-CVD. J Non-Cryst Solids 2011; 357: 3616-22. http://dx.doi.org/10.1016/j.jnoncrysol.2011.07.002

Swain BP, Hwang NM. Effect of negative substrate bias on HWCVD deposited nanocrystalline silicon (nc-Si) films. Solid State Sci 2009; 11: 467-71. http://dx.doi.org/10.1016/j.solidstatesciences.2008.08.004

Luo PQ, Zhou ZB, Li YJ, Lin SQ, Dou XM, RQ. Effects of deposition pressure on the microstructural and optoelectrical properties of B-doped hydrogenated nanocrystalline silicon (nc-Si:H) thin films grown by hot-wire chemical vapor deposition. Microelectron J 2008; 39: 12. http://dx.doi.org/10.1016/j.mejo.2007.10.019

Liskiewicz T, Al-Borno A. DLC coatings in oil and gas production. Journal of Coating Science and Technology 2014; 1; 59-68.

Ossadnik C, Vepřek S, Gregora I. Applicability of Raman scattering for the characterization of nanocrystalline silicon. Thin solid films 1999; 337: 148-51. http://dx.doi.org/10.1016/S0040-6090(98)01175-4

Guo LQ, Ding JN, Yang JC, Cheng GG, Ling ZY. Effects of high hydrogen dilution ratio on surface topography and mechanical properties of hydrogenated nanocrystalline silicon thin. Thin solid films 2011; 519: 6039-43. http://dx.doi.org/10.1016/j.tsf.2011.04.117

Wang JL, Wu EX. Characterization of doped hydrogenated nanocrystalline silicon films prepared by plasma enhanced chemical vapour deposition. Chin Phys B 2007; 16: 848. http://dx.doi.org/10.1088/1009-1963/16/3/049

Zhao ZX, Cui RQ, Meng FY, Zhao BC, Yu HC, Zhou ZB. Nanocrystalline silicon thin films prepared by RF sputtering at low temperature and heterojunction solar cell. Mater Lett 2004; 58: 3963-6. http://dx.doi.org/10.1016/j.matlet.2004.09.004

Ledinsky M, Fekete L, Stuchlik J, Mates T, Fejfar A, Kočka J. Characterization of mixed phase silicon by Raman spectroscopy. J Non-Cryst Solids 2006; 352: 1209-12. http://dx.doi.org/10.1016/j.jnoncrysol.2005.10.072

Wu ZM, Lei QS, Geng XH, Zhao Y, Sun J, Xi JP. Effect of substrate temperature and pressure on properties of microcrystalline silicon films. Chin Phys B 2006; 6: 1320

Tong GB, Rahman A. Semiconductor Electronics, 2006. ICSE '06. IEEE International Conference, Oct. 29, 2006, Proc. Kuala Lumpur, Malaysia, p. 472-6.

Lei QS, Wu ZM, Geng XH, Zhao Y, Xi JP. Influence of the deposition parameters on the transition region of hydrogenated silicon films growth. Chin Phys B 2005; 11: 2342.

Wood DL, Tauc J. Weak absorption tails in amorphous semiconductors. Phys Rev B 1972; 5: 3144. http://dx.doi.org/10.1103/PhysRevB.5.3144

Liao NM, LiW, Jiang YD, et al. Thickness and optical constant determination of hydrogenated amorphous silicon thin film from transmittance spectra of ellipsometer. Acta Phys Sin 2008; 57: 1542-7.

Lien SY, Wang CC, Shen CT, et al. Effects of RF power and pressure on performance of HF-PECVD silicon thin-film solar cells. Thin solid films 2010; 24: 7233-5. http://dx.doi.org/10.1016/j.tsf.2010.04.083

Guo L, Ding J, Yang J, et al. Nanostructure, electrical and optical properties of p-type hydrogenated nanocrystalline silicon films. Vacuum 2011; 85: 649-53. http://dx.doi.org/10.1016/j.vacuum.2010.07.014

Zhang ZG, Su CH. The energy dist ribution of band tall states of nc-Si and it’s optical gap. Acta Energiae Solaris Sinica 1996; 17: 175.

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Published

2014-11-29

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How to Cite

Investigation on Microstructure and Optical Property of Nanocrystalline Silicon Thin Film. (2014). Journal of Coating Science and Technology, 1(2), 111-116. https://doi.org/10.6000/2369-3355.2014.01.02.3

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