Modeling DSC Melting Curves of Isotactic Polypropylene – Source of Information on Isospecificity of Active Centers
DOI:
https://doi.org/10.6000/1929-5995.2013.02.01.2Keywords:
Differential canning calorimetry (DSC), melting point, crystallization, polypropylene (PP), Ziegler-Natta catalystsAbstract
A method is developed for modeling DSC melting curves of isotactic polypropylene produced with single-center and multi-center Ziegler-Natta catalysts. The modeling demonstrates that the use of a simple statistical model of an imperfectly isotactic polymer and the introduction of several assumptions about the crystallization pattern of isotactic blocks in propylene polymers are sufficient for the representation of most characteristic features of their DSC melting curves. This type of modeling can be a source of information on the distribution of active centers with respect to isospecificity. Several examples demonstrate the utility of this modeling approach.
References
(a) Bensason S, Minick J, Moet A, Chum S, Hiltner A, Baer E. J Polym Sci Part B: Polym Phys 1996; 34: 1301. http://dx.doi.org/10.1002/(SICI)1099-0488(199605)34:7<1301::AID-POLB12>3.0.CO;2-E
(b) Bortolussi F, Broyer J-P, Spitz R, Boisson C. Macromol Chem Phys 2002; 203: 2501.http://dx.doi.org/10.1002/macp.200290032
(c) Piel C, Karssenberg FG, Kaminsky W, Mathot VBF. Macromolecules 2005; 38: 6789.http://dx.doi.org/10.1021/ma0505732
(d) Nomura K, Itagaki K, Fujiki M. Macromolecules 2005; 38: 2053.http://dx.doi.org/10.1021/ma050277p
(e) Aitola E, Puranen A, Setälä H, Lipponen S, Leskelä M, Repo T. J Polym Sci Part A: Polym Chem 2006; 44: 6569.http://dx.doi.org/10.1002/pola.21722
Kissin YV. Alkene Polymerization Reactions with Transition Metal Catalysts. Amsterdam: Elsevier 2008, Chapter 2.
Kissin YV. J Polym Sci, Part B: Polym Phys 2011; 49: 195. http://dx.doi.org/10.1002/polb.22164
(a) De Rosa C, Auriemma F, DiCapua A, et al. J Am Chem Soc 2004; 126: 17040. http://dx.doi.org/10.1021/ja045684f
(b) De Rosa C, Auriemma F. Macromolecules 2006; 39: 249.http://dx.doi.org/10.1021/ma051228f
(a) Nifantiev IE, Laishevtsev I, Ivchenko PV, et al. Macromol Chem Phys 2004; 205: 2275. http://dx.doi.org/10.1002/macp.200400238
(b) Resconi L, Guidotti S, Camurati I, et al. Macromol Chem Phys 2005; 206: 1405. http://dx.doi.org/10.1002/macp.200400533
(a) Toyota A, Tsutsui T, Kashiwa N. J Molec Catal 1989; 56: 220. http://dx.doi.org/10.1016/0304-5102(89)80187-7
(b) Tsutsui T, Ishimaru N, Mizuno A, Toyota A, Kashiwa N. Polymer 1989; 30: 1350.http://dx.doi.org/10.1016/0032-3861(89)90059-1
(c) Chien JCW, Tsai WM, Rausch MD. J Am Chem Soc 1991; 113: 8570.http://dx.doi.org/10.1021/ja00022a081
Kakugo M, Miyatake T, Naito Y, Mizunuma K. In: Quirk RP, editor. Transition Metal Catalyzed Polymerizations. Ziegler-Natta and Metathesis Polymerization. New York: Cambridge University Press 1988; p. 624.
(a) Song W, Rausch MD, Chien JCW. J Polym Sci Part A: Polym Chem 1996; 34: 2945; (b) Marques MFV, Bastos QC. J Polym Sci Part A: Polym Chem 2005; 43: 263.
(a) Naga N, Mizunuma K, Sadatoshi H, Kakugo M. Macromolecules 1997; 30: 2197. http://dx.doi.org/10.1021/ma961438f
(b) Ferreira ML, Galland GB, Damiani DE, Villar MA. J Polym Sci Part A: Polym Chem 2001; 39: 2005.http://dx.doi.org/10.1002/pola.1176
(c) Graef SM, Wahner UM, Van Reenen AJ, Brüll R, Sanderson RD, Pasch H. J Polym Sci Part A: Polym Chem 2002; 40: 128.http://dx.doi.org/10.1002/pola.10093
(d) Palza H, Lopez-Majada M, Quijada R, Benavente R, Perez E, Cerrada ML. Macromol Chem Phys 2005; 206: 1221.http://dx.doi.org/10.1002/macp.200500036
(e) Rulhoff S, Kaminsky W. Macromol Chem Phys 2006; 207: 1450.http://dx.doi.org/10.1002/macp.200600176
(a) Venditto V, De Tullio G, Izzo L, Oliva L. Macromolecules 1998; 31: 4027. http://dx.doi.org/10.1021/ma971908l
(b) Abbondanza L, Abis L, Cardi N, Garbassi F, Po R. Macromol Chem Phys 2003; 204: 1428.http://dx.doi.org/10.1002/macp.200350009
Samuels RJ. J Polym Sci Polym Phys 1975; 13: 1417. http://dx.doi.org/10.1002/pol.1975.180130713
(a) Corradini P, Napolitano R, Oliva L, Petraccone V, Pirozzi B, Guerra G. Makromol Chem Rapid Comm 1982; 3: 753. http://dx.doi.org/10.1002/marc.1982.030031018
(b) Guerra G, Petraccone V, Corradini P, et al. J Polym Sci: Polym Phys Ed 1984; 22: 1029.http://dx.doi.org/10.1002/pol.1984.180220608
(a) Petraccone V, Guerra G, De Rosa C, Tuzi A. Makromol Chem Rapid Comm 1984; 5: 631. http://dx.doi.org/10.1002/marc.1984.030051003
(b) Petraccone V, Guerra G, De Rosa C, Tuzi A. Macromolecules 1985; 18: 813.http://dx.doi.org/10.1021/ma00146a037
Paukkeri R, Lehtinen A. Polymer 1993; 34: 4075-4083. http://dx.doi.org/10.1016/0032-3861(93)90669-2
Celli A, Fichera A, Marega C, Marigo C, Paganetto G, Zannetti R. Eur Polym J 1993; 29: 1037. http://dx.doi.org/10.1016/0014-3057(93)90305-Y
Yadav YS, Jain PC. Polymer 1986; 27: 721. http://dx.doi.org/10.1016/0032-3861(86)90130-8
(a) Passingham C, Hendra PJ, Cudby MA, Zichy V, Weller M. Eur Polym J 1990; 26: 631. http://dx.doi.org/10.1016/0014-3057(90)90219-T
(b) Zhu X, Yan D, Tan S, Wang T, Yan D, Zhou E. J Appl Polym Sci 2000; 77: 163.http://dx.doi.org/10.1002/(SICI)1097-4628(20000705)77:1<163::AID-APP22>3.0.CO;2-L
(c) Zhang Z, Gong Y, He T. Eur Polym J 2003; 39: 2315.http://dx.doi.org/10.1016/j.eurpolymj.2003.08.001
Pasquini N. Polypropylene Handbook, 2nd ed. Cincinnati: Hanser Gardner Publ 2005.
Bond EB, Spruiell JE, Lin JS. J Polym Sci Part B: Polym Phys 1999; 37: 3050. http://dx.doi.org/10.1002/(SICI)1099-0488(19991101)37:21<3050::AID-POLB14>3.0.CO;2-L
(a) Campbell RA, Phillips PJ. Polymer 1993; 34: 4809. http://dx.doi.org/10.1016/0032-3861(93)90002-R
(b) Yan RJ, Jiang B. J Polym Sci Polym Phys 1993; 31: 1089.http://dx.doi.org/10.1002/polb.1993.090310904
(c) Thomann R, Wang C, Kressler J, Mülhaupt R. Macromolecules 1996; 29: 8425.http://dx.doi.org/10.1021/ma951885f
(a) Li JX, Cheung WL, Jia DM. Polymer 1999; 40: 1219. http://dx.doi.org/10.1016/S0032-3861(98)00345-0
(b) Hosier IL, Alamo RG, Lin JS. Polymer 2004; 45: 3441.http://dx.doi.org/10.1016/j.polymer.2004.02.071
(c) Nedkov E, Dobreva T. Eur Polym J 2004; 40: 2573.http://dx.doi.org/10.1016/j.eurpolymj.2004.06.017
(d) Juhász P, Varga J, Belina K, Marand H. J Therm Anal Calorim 2004; 69: 561.http://dx.doi.org/10.1023/A:1019916007954
(e) Qiang Z, Yonggang S, Shouke Y, Yihu S, Mao P, Zhang Q. Polymer 2005; 46: 3163.http://dx.doi.org/10.1016/j.polymer.2005.01.097
De Rosa C, Auriemma F. Polym Chem 2011; 2: 2155. http://dx.doi.org/10.1039/c1py00129a
Rishina LA, Galashina NM, Nedorezova PM, et al. Vysokomol Soed 2004; A46: 1493.
Kissin YV. Alkene Polymerization Reactions with Transition Metal Catalysts. Amsterdam: Elsevier 2008, Chapter 4.
Rishina LA, Galashina NM, Gagieva SC, Tuskaev VА, Kissin YV. Eur Polym J 2013; 49: 145.
Press K, Cohen A, Goldberg I, Venditto V, Mazzeo M, Kol M. Angew Chem Int Ed 2011; 50: 3529. http://dx.doi.org/10.1002/anie.201007678
(a) Shelden RA, Fueno T, Tsunetsugu T, Furukawa J. J Polym Sci Part A 1965; 3: 27; (b) Shelden RA, Fueno T, Furukawa J. J Polym Sci Polym Phys Ed 1969; 7: 763.
Kissin YV. Alkene Polymerization Reactions with Transition Metal Catalysts. Amsterdam: Elsevier 2008, Chapter 3.
Soares JBP, Hamielec AE. Polymer 1995; 36: 1639. http://dx.doi.org/10.1016/0032-3861(95)99010-R
Spieckermann F, Wilhelm H, Kerber M, et al. Polymer 2010; 51: 4195. http://dx.doi.org/10.1016/j.polymer.2010.07.009
(a) Barham PJ, Chivers RA, Jarvis DA, Martinez-Salazar J, Keller A. J Polym Sci Polym Lett Ed 1981; 19: 539. http://dx.doi.org/10.1002/pol.1981.130191104
(b) Barham PJ, Jarvis DA, Keller A. J Polym Sci Polym Phys Ed 1982; 20: 1733.http://dx.doi.org/10.1002/pol.1982.180200922
(c) Chivers RA, Barham PJ, Martinez-Salazar D, Keller A. J Polym Sci Polym Phys Ed 1982; 20: 1717.http://dx.doi.org/10.1002/pol.1982.180200921
(d) Wunderlich B. Macromolecular Physics. New York: Academic Press 1980; vol. 3.
(a) Mezghani KK, Campbell RA, Phillips PJ. Macromolecules 1994; 27: 997. http://dx.doi.org/10.1021/ma00082a017
(b) Yamada K, Hikosaka M, Toda A, Yamazaki S, Tagashira K. Macromolecules 2003; 36: 4790.http://dx.doi.org/10.1021/ma021206i
Monakhova TV, Nedorezova PM, Tsvetkova VM, Shlyapnikov YA. Vysokomol Soed 2005; A46: 1.
Arranz-Andrés J, Peña B, Benavente R, Pérez E, Cerrada ML. Eur Polym J 2007; 43: 2357. http://dx.doi.org/10.1016/j.eurpolymj.2007.03.034
Kissin YV, Chadwick JC, Mingozzi I, Morini G. Macromol Chem Phys 2006; 207: 1344. http://dx.doi.org/10.1002/macp.200600074
Kissin YV, Fruitwala HA. J Appl Polym Sci 2007; 106: 3872. http://dx.doi.org/10.1002/app.27090
(a) Natta G, Corradini P, Allegra G. J Polym Sci 1961; 51: 399. http://dx.doi.org/10.1002/pol.1961.1205115602 (b) Giudetti G, Zannetti R, Ajo D, Marigo A, Vidali M. Eur Polym J 1980; 16: 1007.http://dx.doi.org/10.1016/0014-3057(80)90184-6
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